Seamless Metallurgical Clad Pipe | Hot Extruded, Cold Finished & Pickled CRA Lined Tube for High Pressure Boiler & Heat Exchanger – Womic Steel

Short Description:

Seamless metallurgically bonded clad pipe – hot extruded, cold finished, heat treated and pickled. Designed for highintegrity applications in power generation, petrochemical, and high temperature heat transfer. Core materials include ASME SA210 Gr.C, EN102162 carbon steel, and SA213 T91 (X10CrMoVNb91). Cladding options: TP304L (1.4306), UNS N08028 (Alloy 28), and UNS N08825 (Incoloy 825). Manufactured and tested to ASME Section II, EN129522, ASTM E213, and ISO 1089310.


Product Detail

Product Tags

Core Material (Backing)

● SA-210 Gr.C / EN10216-2 (carbon steel – general boiler service)

● SA-213 T91 (X10CrMoVNb9-1 / 1.4903 – creep resistant alloy steel)

Cladding (CRA lining):

● TP304L (1.4306) – austenitic stainless steel for general corrosion resistance

● UNS N08028 (1.4563 / Alloy 28) – high Cr/Ni/Mo/Cu alloy for acidic and chloride environments

● UNS N08825 (2.4858 / Incoloy 825) – nickel-based alloy for sour gas, H₂S/CO₂/chlorides

Process Route: Hot extrusion → cold finishing → heat treatment → pickling. Fully seamless, no longitudinal weld. Metallurgical bond shear strength ≥300 MPa.

Testing & Certification: 100% hydrostatic test, ultrasonic test per ASTM E213 and ISO 10893-10. Compliance with ASME Section II Part A, EN12952-2 (including Part C). Mill certificate EN 10204 Type 3.1 (Type 3.2 with third-party witness optional).

Applications: Boiler water walls, superheaters, reheaters, high pressure heat exchangers, waste heat recovery units, sour service boiler feedwater heaters, refinery heat transfer equipment.

Womic Steel supplies fully traceable seamless clad pipe manufactured to European and ASME codes. Choose your core + cladding combination. Third-party inspection and witness testing available. Contact us for technical datasheets and delivery quote.

1. Product Overview – Seamless Metallurgical Clad Pipe by Hot Extrusion

Seamless metallurgical clad pipe differs fundamentally from mechanically lined pipe or welded clad pipe. The core and cladding are permanently joined by atomic diffusion during hot extrusion, creating a bond that cannot delaminate under thermal cycling, pressure pulsation, or bending.

Why seamless (no longitudinal weld)?
Longitudinal weld seams are potential failure points in high temperature, high pressure cyclic service. Seamless construction eliminates this risk entirely. The hot extrusion process also refines grain structure, improving creep strength and fatigue resistance.

Why hot extrusion + cold finishing + heat treatment + pickling?

● Hot extrusion: Achieves the metallurgical bond at extreme pressure and temperature, reducing cross-section by >8:1 – ensures sound interface.

● Cold finishing (cold drawing / pilgering): Provides precise OD and wall thickness tolerances, excellent surface finish, and increased mechanical properties through work hardening (followed by appropriate heat treatment).

● Heat treatment: Restores ductility, relieves stresses, and develops required microstructure (e.g., normalizing + tempering for SA-210 Gr.C and T91; solution annealing for CRA layers).

● Pickling: Removes oxide scale (magnetite, hematite) left from hot working and heat treatment. The result is a chemically clean, passive surface free from embedded scale – essential for boiler and heat exchanger longevity.

The combination yields a tube that meets the strictest requirements of ASME Section I, EN12952, and PED 2014/68/EU.

2. Material Combinations – Core + Cladding

The three most requested combinations from power plant and petrochemical projects are detailed below. Each addresses a distinct set of service conditions.

2.1 Combination A: SA-210 Gr.C + TP304L (1.4306)

Parameter Core (Backing) Cladding (CRA)
Material SA-210 Gr.C / EN10216-2 TP304L (1.4306)
Standard ASME Section II Part A / EN10216-2 ASME SA-213 / EN10088-3
Typical use Boiler water walls, economizers, low-temp superheaters General corrosion protection against mildly acidic condensate, oxygenated water
Max service temperature ~450°C ~400°C (in corrosive media)
Cladding thickness 1.5 – 3.0 mm
Advantages Good weldability, moderate cost, widely available Low carbon avoids sensitization; good resistance to oxidation and general corrosion

Best for: Conventional coal-fired boiler water wall tubes where the inner surface contacts treated water/steam with occasional acid cleaning or mild contamination.

2.2 Combination B: SA-213 T91 (1.4903) + UNS N08028 (Alloy 28 / 1.4563)

Parameter Core (Backing) Cladding (CRA)
Material SA-213 T91 Type 1 (X10CrMoVNb9-1) UNS N08028 (Alloy 28)
Standard ASME Section II Part A / EN102162 SB668 / EN10088-3
Typical use High temperature superheaters / reheaters, waste heat boilers Acidic flue gas condensate (sulfuric/phosphoric acid), high chlorides
Max service temperature 650°C (creep range) 450°C (in corrosive service)
Cladding thickness 2.0 – 3.5 mm
Advantages Excellent creep rupture strength, oxidation resistance PREN 38-40; resists pitting, crevice corrosion, and stress corrosion cracking in chlorides

Best for: Ultrasupercritical boiler final superheater sections, waste heat recovery boilers downstream of sulfuric acid plants, biomass boilers with high chlorine in flue gas.

2.3 Combination C: SA-210 Gr.C + UNS N08825 (Incoloy 825 / 2.4858)

Parameter Core (Backing) Cladding (CRA)
Material SA-210 Gr.C / EN10216-2 UNS N08825 (Incoloy 825)
Standard ASME Section II Part A / EN102162 SB163 / VdTUV 432
Typical use Boiler feedwater heaters, refinery heat exchangers Sour service (H₂S + CO₂ + chlorides), reducing acids
Max service temperature ~450°C ~450°C (in sour service)
Cladding thickness 2.0 – 3.5 mm
Advantages Cost-effective core, good toughness NACE MR0175 compliant; resists SSC, HIC, and general corrosion in wet H₂S

Best for: Feedwater heaters in gas processing plants, heat exchangers handling produced water or amine solutions, any service requiring high reliability against sour corrosion.

3. Manufacturing Process – From Billet to Pickled Tube

The production route is strictly controlled to ensure bond integrity and traceability.

Stage Operation Key Parameters Inspection
1 Composite billet assembly Core bored, CRA liner inserted, vacuum sealed (≤10 Pa) Visual, dimensional
2 Hot extrusion 1150-1250°C, reduction ratio ≥8:1, speed controlled Temperature recording, visual of extruded surface
3 Cold finishing Cold drawing or pilgering (multiple passes with intermediate annealing) Dimensional check at each pass
4 Heat treatment Normalizing + tempering for core; solution annealing for CRA (depending on grade) Time-temperature chart recorded, hardness test
5 Pickling Immersion in HNO₃+HF bath, followed by water rinse Surface visual, wettability test, scale free confirmation
6 Straightening & cutting Precision straightening, cut to ordered length Laser check of straightness (≤1.5mm/m)
7 NDT & hydrotest Per Section 4 Reports issued
8 End finishing & packing Bevel ends (if specified), oiling, plastic caps Visual, packaging list

4. Inspection & Testing Program – Meeting ASME & EN Standards

All seamless clad pipes undergo the following tests, referenced to the client-specified standards: ASTM E213, ISO 10893-10, EN12952-2 (including part C), and ASME SA-450.

Test Standard Scope Acceptance
100% Ultrasonic testing (longitudinal imperfections) ASTM E213, ISO 10893-10 Full tube length, automated immersion or contact method No defect echo exceeding reference level; linear defects > acceptable length rejected
Hydrostatic test ASME SA-450 / EN12952-2 Each tube, pressure ≥ 1.5× design pressure, hold ≥10s No leakage, permanent expansion within limit
Tensile test (core material) SA-210 / SA-213 / EN10216-2 Per heat / batch Yield, tensile, elongation meet spec
Flattening test ASME SA-450 One per heat / size No cracks until plates distance = 2/3 OD (or as per standard)
Hardness test EN12952-2 C Core and cladding (optional for bond area) Core ≤ spec, cladding ≤ spec
Visual & dimensional SA-450 / EN12952-2 100% OD, wall thickness, length, surface finish, bevel condition

Supplementary tests on request:

● Bond shear strength (push-out test) per API 5LD

● Intergranular corrosion (ASTM A262 Practice E for austenitic cladding)

● Charpy impact (core at specified temperature)

● NACE TM0177 / TM0284 for sour service (on Incoloy 825 clad pipes)

● Positive material identification (PMI) of cladding by XRF

Certificates: EN 10204 Type 3.1 (standard). Type 3.2 with third-party witness (SGS, BV, DNV, TÜV, ABS, LR) available at extra cost.

5. Dimensional Range & Tolerances

Seamless metallurgical clad pipe via hot extrusion + cold finishing is typically available in:

Parameter Range / Tolerance
Outside diameter (OD) 25 mm – 168 mm (1″ – 6″). Larger diameters possible via alternative process (e.g., hot roll bonded + welded) – contact for details.
Core wall thickness 3 mm – 15 mm (depends on OD and pressure rating)
Cladding thickness 1.5 mm – 3.5 mm (minimum 1.5 mm for reliable bond)
Length 6 m – 15 m singular; longer on special request
OD tolerance ±0.5 mm for OD <100mm; ±0.75% for OD ≥100mm
Wall thickness tolerance ±10% (core only; cladding measured separately)
Straightness ≤1.5 mm per meter

Custom dimensions can be discussed.

6. Applications in Detail

6.1 Boiler Water Walls & Economizers (Combination A – SA-210+304L)

● Function: Water absorbs heat from flue gas. Inner surface may see corrosive species from feedwater or occasional acid cleaning. 304L cladding resists low-pH excursions and prevents pitting.

● Advantage over bare carbon steel: Eliminates need for chemical dosing or reduces corrosion allowance, allowing thinner walls and lighter construction.

6.2 Superheaters & Reheaters (Combination B – T91+Alloy 28)

● Challenge: Steam side oxidation, plus external flue gas containing sulfur and chlorides causes high temperature corrosion. T91 provides creep strength; Alloy 28 resists flue gas dewpoint corrosion during startup/shutdown.

● Field benefit: Extended tube life between outages, reduced risk of steam side oxide exfoliation blockage.

6.3 Sour Service Feedwater Heaters (Combination C – SA-210+Incoloy 825)

Environment: High H₂S, CO₂, chlorides in the water/steam side. Carbon steel would fail by sulfide stress cracking within months. Incoloy 825 clad tube provides fully assured sour service performance with significant cost saving compared to solid 825.

6.4 High Pressure Heat Exchangers (all combinations)

Shell & tube heat exchangers where tube side fluid is corrosive but shell side is not. Clad tubes allow use of carbon steel tube sheet (with CRA lining) and full cladding on tube interior.6.5 Waste Heat Recovery (especially sulfuric acid plants)

Hot gas side: up to 600°C; T91 outer (or SA-210 with adequate cooling). Inner surface contacts dilute acid condensate – Alloy 28 or 304L resists attack. Seamless design prevents leakage through longitudinal welds which would be catastrophic in acid service.

9

Surface Condition – Pickled & Passivated

The standard delivery condition for all three combinations is pickled and passivated.

● Pickling: Removes heat scale (iron oxides) formed during hot extrusion and heat treatment. The acid bath (HNO₃ + HF) dissolves scale without attacking the base metal significantly.

● Passivation: After pickling, a thin chromium-rich oxide film forms spontaneously on stainless steel and nickel alloy surfaces, enhancing corrosion resistance.

● Benefit: Ready for installation – no need for additional cleaning or shot blasting. Suitable for high-purity water and sensitive chemical services.

● Optional surface treatments: Oiling for short-term rust prevention (on carbon steel core exposed at ends) – specify if needed.

● If a different surface finish is required (e.g., polishing, shot blasting, no pickling), please request at time of order.

8. Quality Documents & Traceability

Each shipment includes a comprehensive quality dossier:

● EN 10204 Type 3.1 certificate (chemical analysis of core and cladding, tensile results of core, hydrostatic test confirmation, UT report summary)

● Dimensional inspection report (OD, WT, length recorded per bundle)

● Ultrasonic test full logs (or summary with acceptance statement)

● Heat treatment charts (time-temperature curves) for the batch

● Pickling process record (acid concentrations, temperature, duration)

● Packing list and commercial invoice

● Optional: EN 10204 Type 3.2 certificate with third-party witness (additional fee)

All documents are linked to the heat numbers stamped on each tube (low-stress die stamp per ASME SA-450).

9. Delivery & Logistics

● Standard packaging: Plastic end caps, tied in steel-strapped bundles with wooden spacers (for small OD) or individual cradles (for larger OD). Waterproof covering for sea freight.

● Shipping terms: FOB Shanghai/Tianjin (most common), CFR, CIF to any major port. We arrange container or break bulk.

● Lead time (estimate):

● Combination A (SA-210+304L): 12-14 weeks from order confirmation (material stock dependent)

● Combination B (T91+Alloy 28): 16-20 weeks (specialty alloy procurement)

● Combination C (SA-210+Incoloy 825): 16-20 weeks (Incoloy 825 source)

Reduced lead time possible for repeat orders.

●Minimum order quantity: No strict MOQ for trial quantities (e.g., 100-200 meters). Contact for small batch pricing.

10. Frequently Asked Questions (FAQ) – Technical & Commercial

Q1: Why specify seamless clad pipe instead of welded clad pipe?
A: Seamless clad pipe has no longitudinal weld seam in either the core or the cladding. This eliminates a potential failure point under thermal fatigue, hydrogen service, or high pressure. It also avoids any risk of weld undercut or lack of fusion that could initiate corrosion. For boiler and heat exchanger tubes that must pass strict code requirements (ASME Section I, EN12952), seamless is often mandatory.

Q2: Can you provide the clad pipe with the CRA on the outside instead of the inside?
A: Yes. The extrusion process can be reversed: put the CRA on the OD and the carbon/alloy steel on the ID. Please specify at inquiry.

Q3: What is the bond strength of the cladding?
A: Typical measured shear strength from push-out tests is ≥300 MPa. This far exceeds requirements of API 5LD or any recognized standard. For extrusion-bonded clad tube, the interface is considered inseparable under normal service loads.

Q4: Do you perform the ultrasonic test to ASTM E213 or ISO 10893-10?
A: We are equipped to test to both standards. Typically we offer ISO 10893-10 for European-destined orders and ASTM E213 for ASME compliance. Please state your preference; we can also perform a combined test.

Q5: What about EN12952-2 part C – does your heat treatment and testing comply?
A: Yes. Our normalizing + tempering cycles are controlled and recorded as required by EN12952-2 C. The frequency of mechanical testing, flattening, and hydrostatic testing meets or exceeds the standard. We can provide a compliance matrix.

Q6: Is the pickling surface suitable for oxygen / hydrogen / clean steam service?
A: Pickling removes oxides but may leave traces of acid or moisture. For high-purity applications, we recommend additional degreasing and passivation (not included in standard pickling). Please specify this requirement.

Q7: How do I specify the exact dimensions for each combination?
A: Provide:

● Outer diameter (OD) of finished tube

● Core wall thickness (backing steel)

● Cladding thickness (CRA)

● Single length (e.g., 6m, 12m) and total length (m) per combination

Q8: Can you supply these clad tubes in U-bent configuration?
A: Yes, we can bend the finished pickled tube (cold bending with mandrel) followed by stress relief heat treatment and 100% NDT of the bent section. Please request a separate quote for U-bends.

Q9: What third-party inspection options exist?
A: We regularly work with SGS, BV, DNV, TÜV, ABS, and LR. The inspector can witness all or selected tests (hydro, UT, tensile, dimensional). We then issue EN 10204 Type 3.2 certificates.

Q10: Do you keep stock of these clad pipes?
A: We normally produce to order. However, standard items like SA-210+304L in popular diameters (e.g., 63.5×4.88×1.65mm, length 6m) may be available from a previous batch – please inquire.

Q11: What is the cost comparison vs. solid high alloy tube?
A: For the same pressure rating, a clad tube (e.g., T91+Alloy 28) typically costs 40-50% less than a solid Alloy 28 tube of equal OD and wall thickness. For SA-210+Incoloy 825, savings can be 50-60% compared to solid 825. The exact economy depends on cladding thickness and core material.

Q12: Do you have experience with VdTUV certification (e.g., for Incoloy 825 per VdTUV 432)?
A: Yes. We have supplied clad pipes to German plant operators requiring VdTUV approval. We can engage an authorized surveyor for VdTUV material acceptance and provide the required documentation.

Q13: How are the tube ends finished?
A: Standard: plain square cut, deburred. Optionally: beveled (30-35°), threaded (for mechanical couplings), or grooved. Beveled ends can be supplied with CRA buttering (a layer of matching alloy weld metal on the bevel face) to prevent dilution during field welding. Please specify.

Q14: What is the minimum cladding thickness for a reliable extrusion bond?
A: 1.5 mm is our safe minimum for seamless extruded clad pipe. For cladding thickness below 1.5 mm, the bond reliability decreases; we would recommend welded clad pipe instead. For most corrosion allowances, 2.02.5 mm is typical.

Q15: Is there a maximum length limit for seamless clad pipe?
A: Extrusion press capabilities limit single length to approximately 15 m for diameters under 100 mm. For larger diameters, the maximum length tends to shorter (12 m). If longer lengths are required (e.g., for reeling), we can examine the feasibility of cold-drawing longer pieces from extruded mother tubes.

11. Contact Womic Steel for a Technical Quotation

For inquiries on seamless metallurgical clad pipe – hot extruded, cold finished, heat treated, and pickled – please send a list of required combinations (core + cladding, dimensions, quantity, length, certification level). We will respond with a detailed technical offer, delivery time, and price.

Website: www.womicsteel.com
E-mail: sales@womicsteel.com
Tel / WhatsApp / WeChat:

Victor: +86 15575100681

Jack: +86 18390957568