904L Stainless Steel Lined Clad Pipe | UNS N08904 / 1.4539 High Alloy Cladding for Sulfuric & Phosphoric Acid Service – Womic Steel

Short Description:

904L lined bimetal metallurgical clad pipe – inner CRA layer 904L (UNS N08904 / 1.4539) metallurgically bonded to carbon steel or low alloy steel backing. Manufactured by hot roll bonding + JCOE (welded) or by hot extrusion (seamless for small diameters). Designed for high resistance to sulfuric acid, phosphoric acid, formic acid, acetic acid, and chloride stress corrosion cracking. Pickled, passivated, and fully tested.


Product Detail

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Core Material (Backing Steel – multiple options):

● API 5L X52 / X60 / X65 – high strength line pipe for oil & gas / acid transmission

● SA-106 Gr.B – high temperature carbon steel

● SA-210 Gr.C – boiler tube grade

● ASTM A333 Gr.6 – low temperature carbon steel

● ASTM A335 P11 / P22 – Cr-Mo alloy for high temperature (limited use with 904L)

Cladding (CRA liner): 904L (UNS N08904 / 1.4539) – high alloy austenitic stainless steel with 23-28% Ni, 19-23% Cr, 4-5% Mo, 1-2% Cu. PREN ≈ 34. Excellent resistance to reducing acids (sulfuric, phosphoric, formic), good resistance to chloride pitting, superior to 316L in acid service.

Size Range: OD 60 – 1219 mm (welded clad pipe – hot roll + JCOE). OD 25 – 168 mm (seamless extrusion). Core wall thickness 4 – 40 mm. Cladding thickness 2.0 – 4.0 mm (3.0 mm recommended for acid service). Single length up to 15 m (seamless) or 24 m (welded).

Process: Hot roll bonding + JCOE forming (welded) or hot extrusion (seamless). Metallurgical bond shear strength ≥200 MPa (welded) or ≥300 MPa (seamless). 100% UT bond inspection, hydrostatic test, tensile test, flattening, optional PMI and intergranular corrosion test.

Standards: API 5LD (for clad line pipe), ASME Section VIII Div.1, EN 10216-5 (for 904L seamless), ASTM A240 (904L plate). NACE MR0175: 904L is acceptable for sour service only under very limited conditions (low H₂S, low chlorides, low temperature) – not generally recommended.

Applications: Sulfuric acid plant piping, phosphoric acid fertilizer plants, chemical tank farms, seawater cooling systems (high chloride), flue gas desulfurization (FGD) scrubbers, high purity chemical transfer, acetic / formic acid service, pharmaceutical and food processing (high purity).

Womic Steel manufactures 904L lined clad pipe for the most demanding acid handling applications. We combine the corrosion resistance of 904L with the mechanical strength of carbon/alloy steel backing, saving 4060% vs solid 904L pipe. Custom dimensions, thirdparty inspection, EN 10204 Type 3.2 available. Contact us for high alloy clad pipe solutions.

1. Why 904L Clad Pipe? When 316L Is Not Enough

904L (UNS N08904 / 1.4539) is a high alloy austenitic stainless steel developed specifically for applications where 316L fails due to insufficient acid resistance or pitting.

Key differentiators vs 316L:

Property 316L 904L Advantage
Nickel (%) 10-14 23-28 Higher Ni improves acid resistance
Molybdenum (%) 2-3 4-5 Higher Mo improves pitting
Copper (%) 1-2 Cu critical for sulfuric acid resistance
PREN 24-26 34 904L much more pitting resistant
Sulfuric acid resistance Poor below 10% or above 80% Excellent 0-80% at moderate temp 904L is the standard for H₂SO₄ service

Typical acids where 904L excels:

● Sulfuric acid (H₂SO₄) – 0-80% concentration, up to 5060°C

● Phosphoric acid (H₃PO₄) – all concentrations

● Formic acid (HCOOH) and acetic acid (CH₃COOH)

● Dilute hydrochloric acid (HCl) – limited

● Mixed acids (e.g., H₂SO₄ + chlorides)

Why clad? Solid 904L pipe is very expensive (23× price of 316L, 56× price of carbon steel). By using a thin (24 mm) 904L inner layer bonded to a carbon steel outer pipe, you achieve the same corrosion resistance at 4060% lower material cost. The carbon steel core provides mechanical strength at a fraction of the alloy cost.

Common industries: Sulfuric acid production and transport, phosphate fertilizer plants, metal pickling lines, chemical tankers, seawater heat exchangers (high chloride, moderate temperature).

2. Material Specifications – 904L Cladding & Backing Steel Options

2.1 904L Cladding Chemical Composition (% by mass)

Element UNS N08904 (904L)
Carbon (C) ≤0.020
Manganese (Mn) ≤2.00
Silicon (Si) ≤1.00
Phosphorus (P) ≤0.040
Sulfur (S) ≤0.030
Chromium (Cr) 19.0 – 23.0
Nickel (Ni) 23.0 – 28.0
Molybdenum (Mo) 4.0 – 5.0
Copper (Cu) 1.0 – 2.0
Iron (Fe) Balance

The copper addition is critical for sulfuric acid resistance. Without Cu, 316L suffers rapid attack in warm dilute H₂SO₄.

2.2 Mechanical Properties (Room Temperature)

Property 904L Cladding Typical Carbon Steel Backing
Yield Strength (min, MPa) 220 240450 (depending on grade)
Tensile Strength (min, MPa) 490 415535
Elongation (min, %) 35 1825
Hardness (max) 200 HB As per grade

2.3 Corrosion Resistance of 904L – Key Data

Acid Concentration Temperature Corrosion Rate (mm/year)
Sulfuric (H₂SO₄) 10-50% 50°C <0.1 (excellent)
Sulfuric (H₂SO₄) 70-80% 30°C <0.1
Phosphoric (H₃PO₄) 30-85% 80°C <0.1
Formic acid Any 100°C <0.1
Acetic acid Any 100°C <0.1
Seawater 3.5% Cl- 30°C Pitting resistance good (PREN 34)

Limitations: 904L is not recommended for hot (>80°C) concentrated sulfuric acid (>90%) or for high temperature hydrochloric acid service. For those, consider nickel alloys (Alloy C-276).

2.4 Backing Steel Options for 904L Clad Pipe

Backing Steel Standard Strength Main Application for 904L Clad
API 5L X52 / X60 / X65 API 5L PSL2 360450 MPa yield Long distance acid pipelines
SA-106 Gr.B ASTM A106 240 MPa yield Refinery & chemical plant piping
SA-210 Gr.C ASME SA-210 245 MPa yield Acid service boiler / heat exchanger tubes
ASTM A333 Gr.6 ASTM A333 240 MPa yield Low temperature acid pipelines (-45°C)
ASTM A335 P11 / P22 ASTM A335 205275 MPa yield High temperature (>450°C?) Note: 904L limited to ~350°C in acid

Note for high temperature: 904L itself is not suitable for metal temperatures above 350-400°C in corrosive service. The backing steel may withstand higher temperatures, but the cladding will limit overall service temperature. For high temperature acid service (>400°C), consider Alloy 825 or Alloy 28 cladding.

2.5 Dimensional Range

Fabrication Method OD Range (mm) Core WT (mm) Cladding WT (mm) Max Length (m)
Welded (hot roll + JCOE) 219 – 1219 6 – 40 2.0 – 4.0 24
Seamless (extrusion) 25 – 168 4 – 15 2.0 – 3.5 15

Recommended cladding thickness for acid service: 3.0 mm minimum. For very aggressive conditions (e.g., hot sulfuric acid with high flow velocity), we recommend 4.0 mm.

3. Manufacturing Process – Hot Roll Bonding + JCOE (Welded, OD ≥219 mm)

For large diameter acid pipelines, this is the primary route:

Step Description
Plate preparation 904L plate (CRA) and carbon steel plate (backing) are cleaned, stacked (904L on inner side), and vacuum sealed to eliminate oxygen.
Hot roll bonding The stack is heated to 1100-1180°C and rolled at high reduction ratio (≥5:1). The layers bond metallurgically.
Plate NDT 100% ultrasonic testing of the clad plate bond interface.
JCOE forming The clad plate is edgemilled, then formed into an open pipe using JCO presses. 904L becomes the inner surface.
Longitudinal seam welding Two passes: inner pass with 904L filler (or Alloy 625), outer passes with carbon steel filler.
Weld cladding (optional) Inner weld seam may be overlaid with 904L or Alloy 625 for full corrosion coverage.
Heat treatment Stress relief (if required). 904L does not need postweld heat treatment.
NDT & testing Per Section 4.
Pickling & passivation For 904L inner surface, to ensure passive layer.
Final inspection & shipping Bevel, caps, bundling.

For seamless (small diameter, OD ≤168 mm): Centrifugal casting + hot extrusion (similar to previous clad pipe articles). Seamless eliminates the longitudinal weld, preferred for Ubend heat exchangers and high purity lines.

4. Inspection & Testing – 904L Clad Pipe

Since 904L is a high alloy, we pay special attention to cladding composition and corrosion test verification.

Test Standard / Method Scope Acceptance
PMI (XRF) of 904L cladding Positive Material Identification Each tube (or each plate) Confirm Cu, Mo, Ni, Cr within spec
Bond UT Shear wave 100% of clad interface No disbond >50mm; total <2%
Longitudinal UT ASTM E213 / ISO 1089310 100% of tube No rejectable echoes
Hydrostatic test 1.5× design pressure Each tube No leakage
Tensile (backing steel) Per API 5L / A106 / etc. Per heat Meet grade spec
Tensile (bond shear) Pushout or ring shear Per batch ≥200 MPa (welded)
Hardness (904L cladding) HV10 Batch ≤200 HV
Intergranular corrosion ASTM A262 Practice E (on 904L) Per batch (optional) No intergranular attack
Flattening test ASME SA450 Per batch No cracks

Certificates: EN 10204 Type 3.1 (standard). Type 3.2 with third-party witness (SGS, BV, DNV, TÜV) available on request.

Extra tests upon request (chargeable):

● Pitting potential (ASTM G5)

● Copper sulfate – sulfuric acid test for 904L (specific to H₂SO₄ service)

5. Applications – Where 904L Clad Pipe Is the Right Choice

5.1 Sulfuric Acid Plant Piping

Challenge: Hot sulfuric acid (60-80%, 50-80°C) is extremely corrosive to carbon steel and even 316L. 904L has been the standard material for sulfuric acid alkylation, drying towers, and interconnecting piping for decades.

Solution: 904L clad pipe with carbon steel backing (SA-106 Gr.B or API 5L X52). The 904L inner layer handles the acid; carbon steel provides pressure strength and reduces cost.

Example: 24″ OD × 12.7 mm core WT × 3.0 mm 904L cladding, length 12 m. Used in a Middle Eastern sulfur recovery unit.

5.2 Phosphoric Acid Fertilizer Plants

Challenge: Phosphoric acid (30-50%, 50-90°C) contains chlorides, fluorides, and solids. 316L pits and crevice corrodes. 904L provides much better resistance.

Solution: 904L clad pipe with SA-106 Gr.B backing. The copper in 904L is particularly beneficial in phosphoric acid.

5.3 Seawater Cooling / Desalination (High Chloride)

Challenge: 316L can suffer crevice corrosion in stagnant seawater at temperatures above 30-40°C. 904L has higher PREN (34) and resists pitting better.

Solution: 904L clad pipe with API 5L X65 backing for high pressure seawater injection lines. Used in offshore platforms for firewater and cooling systems.

5.4 Chemical Tank Storage & Transfer

Challenge: Storage tanks for acetic acid, formic acid, or mixed organic acids require either very expensive solid alloy or rubber lined carbon steel. Rubber lining can fail.

Solution: 904L clad pipe offers a permanent, maintenance-free corrosion barrier. For tank farm piping, welded clad pipe is ideal.

5.5 Flue Gas Desulfurization (FGD) Scrubbers

Challenge: FGD systems handle gypsum slurries with low pH and chlorides. Many FGD absorber towers and outlet ducts use 904L or higher alloys.

Solution: 904L clad pipe for slurry recirculation lines. Backing can be A106 Gr.B or A333 Gr.6 (if cold).

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6. Why Choose Womic Steel for 904L Clad Pipe?

Strength Details
Experience with high alloys We have produced 904L clad pipe for multiple acid plant projects in China, Middle East, and Southeast Asia.
True metallurgical bond No risk of liner collapse – 904L is permanently bonded to backing steel.
Wide dimensional range Small diameter seamless (extrusion) up to large diameter welded (1219 mm).
Full traceability Each 904L plate heat number is recorded and linked to final pipe. PMI can be performed at multiple points.
Third-party inspection SGS, BV, DNV, TÜV witnessed throughout production. EN 10204 Type 3.2 available.
Cost savings 4060% less expensive than solid 904L pipe of same pressure rating.

7. Packaging, Shipping & Lead Time

● Condition: Pickled and passivated inner 904L surface; outer carbon steel may be oiled or primed.

● End protection: Plastic caps (steel caps for large diameters).

● Bundling: For small diameters (<20″) – bundles with spacers. For large diameters – individual cradles.

● Lead time (first order): 1418 weeks (904L plate sourcing and rolling). Repeat orders: 1012 weeks.

● MOQ: No strict MOQ; trial orders accepted (e.g., 100200 meters). Pricing for small quantities higher.

8. Frequently Asked Questions (FAQ) – 904L Clad Pipe

Q1: When should I choose 904L over 316L for clad pipe?
A: Choose 904L when the service involves sulfuric acid, phosphoric acid, formic/acetic acid, or when 316L shows pitting or general corrosion in your environment. 904L is also better for warm seawater (higher chlorides). If the fluid is only slightly acidic with no chlorides, 316L may suffice.

Q2: What is the maximum temperature for 904L?
A: In corrosive service, 904L is typically limited to 350-400°C. Above that, the material may sensitize or lose corrosion resistance. For high temperature acid service (>400°C), consider Alloy 825 or 625.

Q3: Can 904L be used for sour gas (H₂S) service?
A: NACE MR0175 / ISO 15156 permits 904L for sour service only in very mild conditions: low H₂S partial pressure, low chlorides, pH >3.5, temperature <60°C. For typical sour wet gas, Incoloy 825 is preferred.

Q4: What filler metal should be used for welding 904L clad pipe?
A: For the inner pass (904L to 904L), use Alloy 625 (ERNiCrMo-3) or 904L filler (ER385). Alloy 625 is more common and provides higher safety. Do not use 316L filler.

Q5: Is 904L clad pipe available in small diameters (e.g., 2″) for instrumentation?
A: Yes, through our seamless extrusion process. Minimum OD is approximately 25 mm (1″). Cladding thickness 2.02.5 mm.

Q6: How does 904L compare to Alloy 28 (UNS N08028)?
A: Both are high alloy austenitics with similar PREN (34 vs 38). Alloy 28 has higher Cr and Ni, and better resistance to high chloride + high temperature pitting. For sulfuric acid, both are excellent. Alloy 28 is slightly more expensive. 904L is more common in North American acid plants; Alloy 28 in European specifications.

Q7: Can you supply 904L clad pipe with A333 Gr.6 backing for low temperature service?
A: Yes. 904L remains ductile at low temperature; the A333 Gr.6 backing is impact tested at -45°C. The combination is suitable for arctic acid pipelines (rare but possible).

Q8: Do you provide assurance that the cladding is free from dilution by carbon steel?
A: Yes. The vacuum hot roll bonding process prevents oxidation and minimizes diffusion. We perform PMI on the cladding surface to verify composition. The dilution zone is typically only a few microns thick and is not exposed to the fluid.

Q9: What is the typical yield strength of 904L cladding?
A: 904L has a yield strength of approximately 220 MPa (32 ksi) in the annealed condition. This is lower than carbon steel backing but the cladding thickness is small; the carbon steel core carries the hoop stress. For pressure design, we use the backing steel wall thickness only; the cladding is considered a corrosion allowance.

Q10: Do you offer beveled ends with 904L buttering?
A: Yes. We can prepare bevels (30-35°, 1.6 mm land) and apply a weld overlay (buttering) of Alloy 625 or 904L filler on the bevel face. This prevents dilution of the 904L cladding during field girth welding.

Q11: Can you supply 904L clad heat exchanger U-bend tubes?
A: Yes, for seamless clad pipe (OD ≤168 mm). We cold bend, stress relieve, and 100% NDT (PT or ET) the bend area. U-bends for acid services are common in chemical plants.

Q12: How do I order a small trial quantity?
A: Provide OD, core WT, cladding thickness, length (m), and backing steel grade. We will quote a trial batch (e.g., 50100 meters). Expect a price premium for small quantities.

9. Ordering Checklist for 904L Clad Pipe

To ensure correct specification, please provide:

● Backing steel grade (API 5L X52/60/65, SA-106 Gr.B, SA-210 Gr.C, A333 Gr.6, or A335 P11/P22)

● Outer diameter (OD) and core wall thickness

● 904L cladding thickness (recommend 3.0 mm for acid service)

● Length per piece and total length (meters)

● Fabrication method (welded for OD ≥219 mm; seamless for OD ≤168 mm)

● Applicable standard (API 5LD, ASME, EN, or customer spec)

● Inspection level (Type 3.1 standard; Type 3.2 with thirdparty)

● End finishing (plain, beveled, beveled + 904L buttering)

● Delivery term (FOB China port, CIF destination port)

Womic Steel will respond with a technical datasheet, commercial quote, and quality plan.

10. Contact Womic Steel – High Alloy Clad Pipe Specialist

If you are looking for a 316L lined clad pipe with any standard carbon or alloy steel backing, contact us for a free technical consultation and noobligation quote.

Website: www.womicsteel.com
E-mail: sales@womicsteel.com
Tel / WhatsApp / WeChat:

Victor: +86 15575100681

Jack: +86 18390957568

Womic Steel – Tailored 316L clad pipe solutions for CO₂ service, boiler, heat exchanger, low temperature, and high temperature applications.